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System Information in Quantum Mechanics

Quantum mechanics is an abrupt shift in interpretation from our classical models. In Schrödinger's model for particle mechanics, the function describing classical position $x(t)$ is replaced with a statistical object that we call the wavefunction $ \Psi(x,t)$.

  • In Classical Mechanics: a particle's dynamics are completely described by its position $x(t)$ over time t. Solves a second-order ordinary differential equation.
  • In Schrödinger's Quantum Mechanics: information about a particle system is encoded in a probability wavefunction, $\Psi(x,t)$, which spreads across space and evolves in time. Solves a linear partial differential equation.

Motion in Newtonian Mechanics

To understand how $\Psi(x,t)$ encodes observable information, like particle position, we should start by describing classical motion. In Newton's formulation, a particle's position in three-dimensional space ($\vect{r}$) is described by the differential equation:

$$ \bbox[8px,border:1px solid black] {\vect{F}= \frac{d\vect{p}}{dt} = m \frac{d^2\vect{r}}{dt^2}} \tag{Eq. 1}$$

Eq. 1 - Newton's equation of motion states that acceleration is the second time-derivative of system position. If a system's mass is non-constant, m is not a scalar.

Solutions to (Eq. 1) will describe a system's motion exactly for all time and space; this is a deterministic model for motion. This ordinary differential equation (ODE) leads to the well-known relationships between $x(t)$ $v(t)$ and $a(t)$:

$$ \bbox[8px,border:1px solid black] {a(t) = \frac{d v(t)}{dt} = \frac{d^2 x(t)}{dt^2}}$$

Motion and Energy in Schrödinger's Quantum Mechanics

Schrödinger's analog to Newton's Equation is a complex-valued energy conservation equation:

$$ \bbox[8px,border:1px solid black]{ i \hbar \frac{\partial{\Psi(x,t)}}{\partial{t}} = - \frac{\hbar^2}{2m} \frac{\partial^2 \Psi}{\partial x^2} + V(x,t) \Psi(x,t) } \tag{Eq. 2} $$

Eq. 2 - Schrödinger's Equation for the energy and motion of a particle. Partial differential equation whose solutions are functions of both position and time: $\Psi(x,t)$.

This is a linear, second-order, partial differential equation, with a similar form to the wave equation. Obtaining analytical solutions to this PDE for a given system potential, $V(x,t)$, is almost never trivial and often it is impossible.


Where is Classical Position Encoded in Schrödinger's Equation?

Schrödinger's Equation seems bizarre compared to Newton's; solutions ($\Psi$) are fields, from which observable quantities may be extrapolated. while the latter uses a simple, three-dimensional vector ($\vect{r}$).

If classical mechanics successfully predicts behavior of many [mainly macroscopic] systems, then those results should fall out of quantum-mechanical models as well. That is, these equations must agree within classical limits of systems accurately described by classical models.

  • In other words, we need to verify that classical mechanics is an approximation for quantum mechanics.

Schrödinger's equation has solutions not of $x(t)$, but of a wavefunction $\Psi(x,t)$. The square-amplitude of $\Psi$ is related to $x(t)$ statistically (Gasiorowicz, pp. 46):

$$ \bbox[8px,border:1px solid black]{ \lt x \gt = \int_{- \infty}^{+ \infty} \left[\Psi^* \hat{x}\ \Psi \right]\ dx} \tag{Eq. 3}$$

Eq. 3 - Expectation value for position as a function of time. Here, $\Psi^*(x,t)$ denotes the complex conjugate of $\Psi(x,t)$.

In quantum mechanics, $ \hat{x}$ is an operator; $\hat{x}$ represents the operator for position. Operating on $\Psi$ with functional operators produces expectation values of physically significant quantites, such as momentum and position.

  • The wavefunction is not directly observable, yet its probability density (|$\Psi^2$|) is physically significant and may be imaged with very modern technology.
  • Here, $\lt x(t) \gt$ is the probability of finding our particle between $- \infty$ and $+ \infty$ (entire x-axis). This boundary may be finite, and (Eq. 3) must be a convergent integral if it is to meaningfully describe observable quantities (Gasiorowicz, pp. 48).


Operating on $\Psi(x,t)$